SYNTHESIS AND PROPERTIES OF CALCIUM-ALUMINOFERRITE CEMENT  USING MAN-MADE MATERIALS

Ivan Borisov; Alexey Novosyolov; Mariya Nikitina; Vladimir Manuilov

doi:10.62980/2076-0655-2024-108-117

UDC

666.9.04

CSCSTI

61.35

VAK Russia

2.6.14

SYNTHESIS AND PROPERTIES OF CALCIUM-ALUMINOFERRITE CEMENT USING MAN-MADE MATERIALS

Published in Technique and technology of silicates · Pages 108–117 · Rubric: MAIN RUBRIC

DOI: https://doi.org/10.62980/2076-0655-2024-108-117 · EDN: QHZOLJ

Received: 05.02.2024 Accepted: 03.04.2024 Published: 03.07.2024 Language of publication: RUS

Authors

Ivan Borisov

Alexey Novosyolov

Mariya Nikitina

Vladimir Manuilov

Ivan Borisov

Academic degree: doctor of technical sciences

Science rang: docent

Belgorod State Technological University named after V.G. Shukhov Head of the Department · Department of Cement and Composite Materials Technology · Russian Federation · Belgorod

Alexey Novosyolov

Academic degree: candidate of technical sciences

Belgorod State Technological University named after V.G. Shukhov Associate Professor · Department of Cement and Composite Materials Technology · Russian Federation · Belgorod

Mariya Nikitina

Belgorod State Technological University named after V.G. Shukhov Department of Cement and Composite Materials Technology · Russian Federation · Belgorod

Vladimir Manuilov

Academic degree: candidate of technical sciences

OOO TP-ENGINEERING Director of the Department for Technological Equipment Adjustment · Russian Federation · Belgorod

ABSTRACT

The article discusses the production of calcium-aluminoferrite clinker (cement) from a three-component mixture (by sin-tering), where 56.2-57.4 wt.% of the mixture consists of aluminum– and iron-containing man-made waste. It was found that the use of man-made waste as a component of the raw material mixture leads to a decrease in the amount of waste generat-ed by 4.9-5.4%, based on the production of 300,000 tons of calcium-alumoferrite cement per year. The results of qualitative and quantitative X–ray phase analysis of the clinkers obtained are presented, which indicate the formation of calcium aluminates (CA,C3A,C12A7), calcium aluminoferrite(Ca2(Al,Fe)2O5) and calcium silicate (α-, β-C2S) as the main clinker phases in all samples. Clinker phases of aluminate and calcium aluminoferrite are formed not in pure form, but with the introduction of impurity elements (Mg2+, Ti4+). Determination of the hydration activity of CAFC showed that the quantitative ratio of clinker phases CA:Ca2(Al,Fe)2O5 = 38.8:33.8 (CAFC I) and CA:Ca2(Al,Fe)2O5 = 27.6:23.9 (CAFC II) leads to an increase in the strength of cement stone in the initial periods of hardening by 48 and 32 MPa, and in later periods (28 days) - to an increase in strength by 28 and 8 MPa, respectively.

KEYWORDS

technogenic materials, calcium-alumoferrite cement, phase composition, calcium aluminates, calcium aluminoferrite, energy and resource conservation

Funding

The work was carried out within the framework of the University Development Program “PRIORITY 2030”. Project No. 12/22 “Development of technology and production of special shrinkage-free and weakly expanding composite binders”

1. Degel' R., Freling K., Hansman T. [i dr.]. Koncepciya bezothodnogo metallurgicheskogo proizvodstva //Chernye metally. – 2016. № 4. – S. 40-49. EDN: https://elibrary.ru/WDKUEP

2. Novye puti ispol'zovaniya othodov metallurgicheskoy i energeticheskoy promyshlennosti v tehnologii vyazhuschih / M.A. Suhanov, S.N. Efimov, N.N. Dolgopolov [i dr.] // Stroitel'nye materialy. – 1991. – № 7. – S. 22–23.

3. Oficial'nyy sayt Rosstat https://rosstat.gov.ru/

4. Liew K.M., Sojobi A.O., Zhang L.W. Green concrete: Prospects and challenges. Construction and Building Materials. - 2017. Vol. 156. - Pp. 1063-1095. DOI: https://doi.org/10.1016/j.conbuildmat.2017.09.008; EDN: https://elibrary.ru/YHBMFK

5. Tamanna K., Raman S., Jamil M., Hamid R. Utilization of wood waste ash in construction technology: A review. Construction and Building Materials. – 2020. Vol. 237. 117654.

6. Zulkernain N.H., Gani P., Chuck Chuan N., Uvarajan T. Utilisation of plastic waste as aggregate in construction materials: A review. Construction and Building Materials. – 2021. Vol. 296. 123669.

7. Poudyal L., Adhikari K. Environmental sustainability in cement industry: An integrated approach for green and economical cement production. Resources, Environment and Sustainability. – 2021. Vol. 4. 100024.

8. Tsakiridis P.E., Papadimitriou G.D., Tsivilis S., Koroneos C. Utilization of steel slag for Portland cement clinker production. Journal of Hazardous Materials. – 2008. Vol. 152. - Pp. 805-811. DOI: https://doi.org/10.1016/j.jhazmat.2007.07.093; EDN: https://elibrary.ru/KJXXVX

9. Perfilov V. A. Utilizaciya promyshlennyh othodov dlya povysheniya ekologicheskoy bezopasnosti okruzhayuschey sredy // Yug Rossii: ekologiya, razvitie. – 2016. – T. 11, № 2. – S. 205-212. EDN: https://elibrary.ru/WELZST

10. Tomashevskiy V. A. Perspektivy ispol'zovaniya othodov PAO «Severstal'» v cementnoy promyshlennosti // Iniciativy molodyh - nauke i proizvodstvu: Sbornik statey IV Vserossiyskoy nauchno-prakticheskoy konferencii molodyh uchenyh i studentov, 30 noyabrya 2022 goda. – Penza, 2022. – S. 515-516. EDN: https://elibrary.ru/CPGSHZ

11. Klassen V. K., Dolgova E. P., Morozova I. A., Dolgov V. M. Proizvodstvo cementa na osnove tehnogennyh materialov Belgorodskoy oblasti // Naukoemkie tehnologii i innovacii, 09–10 oktyabrya 2014 g. – Belgorod, 2014. – S. 112-117. EDN: https://elibrary.ru/TCLKMZ

12. Krutilin A. A., Krapchetova T. V., In'kova N. A., Pahomova O. K. Ispol'zovanie ferritno-kal'cievogo shlaka v kachestve zhelezosoderzhaschego komponenta pri proizvodstve portlandcementnogo klinkera // Vestnik Tomskogo gosudarstvennogo arhitekturno-stroitel'nogo universiteta. – 2021. – T. 23, № 5. – S. 118-126. – DOIhttps://doi.org/10.31675/1607-1859-2021-23-5-118-126. EDN: https://elibrary.ru/IIVXLL

13. Borisov I. N., Manuylov V. E. Energo- i resursosberezhenie v proizvodstve cementa pri kompleksnom ispol'zovanii tehnogennyh materialov // ALITinform: Cement. Beton. Suhie smesi. – 2009. – № 6(12). – S. 50-58. EDN: https://elibrary.ru/OONMKL

14. Krivoborodov Yu.R. Special'nye cementy: raznovidnosti, svoystva i primenenie // Tehnika i tehnologiya silikatov. 2023. T. 30. № 1. S. 84 – 91 EDN: https://elibrary.ru/BANTUI

15. Samchenko S.V. Sul'fatirovannye alyumoferrity kal'ciya i cementy na ih osnove./ Samchenko S. V.; Federal'noe agentstvo po obrazovaniyu, RHTU im. D. I. Mendeleeva, Izdatel'skiy centr M. 2004. 120 s. EDN: https://elibrary.ru/QNDUNJ

16. Kuznecova T.V., Krivoborodov Yu.R., Samchenko S.V. Himiya, sostav i svoystva special'nyh cementov /V sbornike: Himiya i himicheskaya tehnologiya na rubezhe tysyacheletiy. materialy nauchno-prakticheskoy konferencii. Tomskiy politehnicheskiy universitet (TPU). 2000. S. 96-98. EDN: https://elibrary.ru/TOEXOZ

17. Samchenko S.V., Zorin D.A. Vliyanie dispersnosti rasshiryayuschegosya komponenta na svoystva cementov // Tehnika i tehnologiya silikatov. 2006. T. 13. № 2. S. 2-7. EDN: https://elibrary.ru/KWMZHD

18. Samchenko S.V., Korshunov A.V., Zorin D.A., Tobolev P.D. Fiziko-mehanicheskie i deformacionnye harakteristiki polimineral'nyh vyazhuschih kompoziciy na osnove sul'foalyumoferritov kal'ciya // Tehnika i tehnologiya silikatov. – 2023. – T.30, № 3. – S. 230-240. https://tsilicates.ru/2023_tts3 EDN: https://elibrary.ru/UEVZTJ

19. Isteri V., Ohenoja K., Hanein T., Kinoshita H., Kletti H., Rößler C., Tanskanen P., Illikainen M., Fabritius T. Ferritic calcium sulfoaluminate belite cement from metallurgical industry residues and phosphogypsum: Clinker production, scale-up, and microstructural characterization. Cement and Concrete Research. – 2022. Vol. 154. 106715.

20. Kuznecova, T.V. Special'nye cementy na osnove othodov promyshlennosti [Tekst] // Cement. - 1984. №4. – S. 6-8.

21. Grebenyuk A. A., Borisov I. N. Zhelezosoderzhaschie tehnogennye othody dlya polucheniya rasshiryayuschihsya kompoziciy // Naukoemkie tehnologii i innovacii: sbornik dokladov mezhdunarodnoy nauchno-prakticheskoy konferencii, 06–07 oktyabrya 2016 goda. – Belgorod, 2016. - S. 91-97. EDN: https://elibrary.ru/YIDGSP

22. Ivashina M. A. Ispol'zovanie tehnogennyh materialov v proizvodstve sul'foalyuminatnogo klinkera // Himiya i himicheskaya tehnologiya v XXI veke : Materialy XIX Mezhdunarodnoy nauchno-prakticheskoy konferencii imeni professora L.P. Kuleva studentov i molodyh uchenyh, 21–24 maya 2018 goda. – Tomsk, 2018. – S. 73-74. EDN: https://elibrary.ru/XVVYHZ

23. Serpichev A.S., Sycheva L.I. Ispol'zovanie tehnogennyh othodov pri poluchenii belitsul'foalyuminatnogo cementa // Uspehi v himii i himicheskoy tehnologii. – 2022. – T. 36, № 3(252). – S. 130-133. EDN: https://elibrary.ru/HAFENX

24. Grebenyuk A.A., Borisov I.N., Davidyuk A.S. Nikitina M.A. Formirovanie tverdofazovyh rastvorov pri sinteze vysokoosnovnogo ferritnogo klinkera // Tehnika i tehnologiya silikatov. 2022. T. 29. №3. S. 217 – 230. EDN: https://elibrary.ru/YSXIOX

25. Hewlett P., Liska M. Lea's Chemistry of Cement and Concrete. Butterworth-Heinemann, Oxford, 2019.

26. Kuznecova T. V., Talaber Y. Glinozemistyy cement. – Moskva: Stroyizdat. - 1988. s. 272. EDN: https://elibrary.ru/YQMMAP

27. Krivoborodov Y. R., Kuznetsova T. V., Samchenko S. V. Structural Changes in Refractory Calcium Aluminate Cement Concrete. Refractories and Industrial Ceramics. – 2018. № 59, Pp. 151-155. DOI: https://doi.org/10.1007/s11148-018-0197-1; EDN: https://elibrary.ru/BREKVE

GOST

Borisov I. N., Novosyolov A. G., Nikitina M. A., Manuilov V. E. SYNTHESIS AND PROPERTIES OF CALCIUM-ALUMINOFERRITE CEMENT USING MAN-MADE MATERIALS // . 2024. pp. 108-117. DOI: https://doi.org/10.62980/2076-0655-2024-108-117. EDN: QHZOLJ. (Date of access 19.08.2026).

MLA

Ivan Borisov, Novosyolov A. G., Nikitina M. A., Manuilov V. E.. "SYNTHESIS AND PROPERTIES OF CALCIUM-ALUMINOFERRITE CEMENT USING MAN-MADE MATERIALS." (2024): 108-117. DOI: https://doi.org/10.62980/2076-0655-2024-108-117. EDN: QHZOLJ.

APA

Borisov I. N., Novosyolov A. G., Nikitina M. A., Manuilov V. E. (2024). SYNTHESIS AND PROPERTIES OF CALCIUM-ALUMINOFERRITE CEMENT USING MAN-MADE MATERIALS. , 108-117. https://doi.org/10.62980/2076-0655-2024-108-117 EDN: QHZOLJ.

Chicago

Ivan Borisov, Novosyolov A. G., Nikitina M. A., Manuilov V. E.. "SYNTHESIS AND PROPERTIES OF CALCIUM-ALUMINOFERRITE CEMENT USING MAN-MADE MATERIALS." , no. (2024): 108-117. https://doi.org/10.62980/2076-0655-2024-108-117. EDN: QHZOLJ.

WIKI

{{cite journal | author = Borisov I. N., Novosyolov A. G., Nikitina M. A., Manuilov V. E. | title = SYNTHESIS AND PROPERTIES OF CALCIUM-ALUMINOFERRITE CEMENT USING MAN-MADE MATERIALS | journal = | year = 2024 | pages = 108-117 | doi = 10.62980/2076-0655-2024-108-117 }} EDN: QHZOLJ

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