Technique and technology of silicates Technique and technology of silicates Техника и технология силикатов 2076-0655 90158 10.62980/2076-0655-2024-274-283 dvzayu ОСНОВНАЯ РУБРИКА MAIN RUBRIC ОСНОВНАЯ РУБРИКА KINETICS OF MINERAL FORMATION IN THE SYNTHESIS OF SULFOALUMINATE CLINKER BASED ON INDUSTRIAL WASTE КИНЕТИКА МИНЕРАЛООБРАЗОВАНИЯ ПРИ СИНТЕЗЕ СУЛЬФОАЛЮМИНАТНОГО КЛИНКЕРА НА ОСНОВЕ ПРОМЫШЛЕННЫХ ОТХОДОВ Мин Хеин Хтет Min Hein Htet minhein29@mail.ru Потапова Екатерина Николаевна Potapova Ekaterina Nikolaevna potapova.e.n@muctr.ru Рудомазин Виктор Викторович Rudomazin Viktor Viktorovich v.rudomazin@eipc.center 07 11 2024 07 11 2024 31 3 274 283 28 08 2024 18 09 2024 https://tsilicates.ru/en/nauka/article/90158/view

Исследована кинетика минералообразования при синтезе сульфоалюминатного клинкера с использованием в качестве сырьевых компонентов промышленных отходов. Применение промышленных отходов позволяет синтезировать качественный сульфоалюминатный клинкер и цемент на его основе. Различными физико-химическими метода-ми анализа показано изменение количества образующихся сульфоалюмината кальция и майенита при обжиге сырь-евых смесей при температуре 1250, 1300 и 1350 ℃ в течение 30, 60 и 90 мин. Проведен кинетический анализ про-цесса минералообразования по 12 кинетическим уравнениям, что позволило оценить скорость реакции формирования клинкера и оптимизировать процесс синтеза. Экспериментально установлены зависимости между скоростью образования клинкерных минеральных фаз и различными параметрами реакционной смеси. Полученные результаты могут быть использованы для улучшения технологических процессов производства сульфоалюминатных клинкеров на основе отходов и снижения энергозатрат на данный процесс.

The kinetics of mineral formation in the synthesis of sulfoaluminate clinker using industrial waste as raw materials has been studied. The use of industrial waste makes it possible to synthesize high-quality sulfoaluminate clinker and cement based on it. Various physico-chemical analysis methods have shown a change in the amount of calcium sulfoaluminate and mayenite formed during the firing of raw mitures at temperatures of 1250, 1300 and 1350 ° for 30, 60 and 90 minutes. A kinetic analysis of the mineral formation process was carried out using 12 kinetic equations, which made it possible to es-timate the reaction rate of clinker formation and optimize the synthesis process. The dependences between the rate of for-mation of clinker mineral phases and various parameters of the reaction mixture have been experimentally established. The results obtained can be used to improve the technological processes for the production of sulfoaluminate clinkers based on waste and reduce energy consumption for this process.

 сульфоалюминатный клинкер промышленные отходы энергоффективность рентгенофазовый анализ кинетика минералобразования sulfoaluminate clinker energy efficiency X-ray phase analysis mineral formation

Maddalena, R. Can Portland cement be replaced by low carbon alternative materials? A study on the thermal properties and carbon emissions of innovative cements/R. Maddalena, J.J Roberts, A. Hamilton//J Clean Prod 2018. Vol.186. p.933-42. Maddalena, R. Can Portland cement be replaced by low carbon alternative materials? A study on the thermal properties and carbon emissions of innovative cements/R. Maddalena, J.J Roberts, A. Hamilton//J Clean Prod 2018. Vol.186. p.933-42. Liu, Z. Experimental and numerical investigations on the inhibition of freeze–thaw damage of cement-based materials by a methyl laurate/diatomite microcapsule phase change material/Z. Liu., J. Jiang., X.Jin.,Y. Wang., Y. Zhang // J Energy Storage 2023. Vol.68. 107665. Liu, Z. Experimental and numerical investigations on the inhibition of freeze–thaw damage of cement-based materials by a methyl laurate/diatomite microcapsule phase change material/Z. Liu., J. Jiang., X.Jin.,Y. Wang., Y. Zhang // J Energy Storage 2023. Vol.68. 107665. Schneider, M., Sustainable cement production present and future/ M. Schneeider, M. Romer., M. Tschudin., H. Bolio// Cement Concr Res 2011. Vol. 41. № .7. p. 642-50. Schneider, M., Sustainable cement production present and future/ M. Schneeider, M. Romer., M. Tschudin., H. Bolio// Cement Concr Res 2011. Vol. 41. № .7. p. 642-50. Taylor, H.F.W. Cement Chemistry. Published by Thomas Telford Publishing, Thomas Telford Services Ltd, 1 Heron Quay, London E144JD. 1997. 457 р. Taylor, H.F.W. Cement Chemistry. Published by Thomas Telford Publishing, Thomas Telford Services Ltd, 1 Heron Quay, London E144JD. 1997. 457 r. Потапова, Е.Н. Технологические, технические и организаци-онно-управленческие решения для устойчивого развития и декарбонизации цементной отрасли /Е.Н. Потапова., Т.В. Гусева., Т.О. Толстых, Бубнов А.Г//Техника и технология силикатов. 2023. Т. 30, № 2.С.104-115. https://tsilicates.ru/2023_tts2. Potapova, E.N. Tehnologicheskie, tehnicheskie i organizaci-onno-upravlencheskie resheniya dlya ustoychivogo razvitiya i dekarbonizacii cementnoy otrasli /E.N. Potapova., T.V. Guseva., T.O. Tolstyh, Bubnov A.G//Tehnika i tehnologiya silikatov. 2023. T. 30, № 2.S.104-115. https://tsilicates.ru/2023_tts2. Gartner, E. A review of alternative approaches to the reduction of CO2 emissions associated with the manufacture of the binder phase in concrete/E. Gartner., H. Hirao// Cement and Concrete Re-search. 2015. Vol.78. Pp.126-142. https://doi.org/10.1016/j.cemconres.2015.04.012. Gartner, E. A review of alternative approaches to the reduction of CO2 emissions associated with the manufacture of the binder phase in concrete/E. Gartner., H. Hirao// Cement and Concrete Re-search. 2015. Vol.78. Pp.126-142. https://doi.org/10.1016/j.cemconres.2015.04.012. Leitan, F. A look ahead: what will the cement plant look like in the near future/ F. Leitan// Vzglyad vpered: kakim budet tsementnyy zavod v blizhayshem budushchem. Cement and its application. Tsement i yego primeneniye. 2020. 1. pp.124-128. Leitan, F. A look ahead: what will the cement plant look like in the near future/ F. Leitan// Vzglyad vpered: kakim budet tsementnyy zavod v blizhayshem budushchem. Cement and its application. Tsement i yego primeneniye. 2020. 1. pp.124-128. Concrete is more than a material. It’s about life/ Global Cement and Concrete Association (GCCA) of 03.05.2021. Concrete is more than a material. It’s about life/ Global Cement and Concrete Association (GCCA) of 03.05.2021. Turner, LK. Carbon dioxide equivalent (CO2-e) emissions. a comparison between geopolymer and OPC cement concrete/L.K. Turner, FG Collins // Construct Build Mater. 2013. Vol. 43. p. 125–30. Turner, LK. Carbon dioxide equivalent (CO2-e) emissions. a comparison between geopolymer and OPC cement concrete/L.K. Turner, FG Collins // Construct Build Mater. 2013. Vol. 43. p. 125–30. Hienola, A. The role of anthropogenic aerosol emission reduction in achieving the Paris Agreement’s objective/A. Hienola A., J. Pietikainen, D.O. Donnell, Partanen AI, H. Korhonen, A. Laaksonen// Vienna, Austria. 2017. Hienola, A. The role of anthropogenic aerosol emission reduction in achieving the Paris Agreement’s objective/A. Hienola A., J. Pietikainen, D.O. Donnell, Partanen AI, H. Korhonen, A. Laaksonen// Vienna, Austria. 2017. Winnefeld, F. Using gypsum to control hydration kinetics of CSA cements /F, Winnefeld., L.H., Martin L.H., C.J Müller., B. Lothenbach // Construct. Build. Mater. 2017. 155. Pp.154-163. https://doi.org/10.1016/j.conbuildmat.2017.07.217. Winnefeld, F. Using gypsum to control hydration kinetics of CSA cements /F, Winnefeld., L.H., Martin L.H., C.J Müller., B. Lothenbach // Construct. Build. Mater. 2017. 155. Pp.154-163. https://doi.org/10.1016/j.conbuildmat.2017.07.217. Gartner, E. Low-CO2 cements based on calcium sulfoalumi-nates/ E. Gartner, K .Quillin // Sustainability in the Cement and Concrete Industry, Norwegian Cement Association, 2007. Vol. 16. Pp. 95-105. Gartner, E. Low-CO2 cements based on calcium sulfoalumi-nates/ E. Gartner, K .Quillin // Sustainability in the Cement and Concrete Industry, Norwegian Cement Association, 2007. Vol. 16. Pp. 95-105. Tao, Y. Recent progress and technical challenges in using calcium sulfoaluminate (CSA) cement /.Y. Tao., A.V.Rahul.,M.K Mohan.,G.D Schutter.,K.V Tittelboom//.Cement Concr. Compos. 2022. Article 104908. DOI: 10.1016/j.cemconcomp.2022.104908. Tao, Y. Recent progress and technical challenges in using calcium sulfoaluminate (CSA) cement /.Y. Tao., A.V.Rahul.,M.K Mohan.,G.D Schutter.,K.V Tittelboom//.Cement Concr. Compos. 2022. Article 104908. DOI: 10.1016/j.cemconcomp.2022.104908. Никитина, М.А. Оценочная характеристика качества кальциево-алюминатного цемента с использованием техногенных материалов/ М.А. Никитина., И.Н Борисов., Т.И Тимошенко// АЛИТИНФОРМ: Цемент. Бетон. Сухие смеси. 2020. 4(61). С. 16-25. Nikitina, M.A. Ocenochnaya harakteristika kachestva kal'cievo-alyuminatnogo cementa s ispol'zovaniem tehnogennyh materialov/ M.A. Nikitina., I.N Borisov., T.I Timoshenko// ALITINFORM: Cement. Beton. Suhie smesi. 2020. 4(61). S. 16-25. Li, H. Microwave sintering of sulphoaluminate cement with utility wastes/H. Li, DK Agrawal, J. Cheng, MR. Silsbee. // Cement Concr. Res. 2001. p. 311257 -61. Li, H. Microwave sintering of sulphoaluminate cement with utility wastes/H. Li, DK Agrawal, J. Cheng, MR. Silsbee. // Cement Concr. Res. 2001. p. 311257 -61. Więckowski, A. Automating CSA cement-based reinforced monolithic ceiling construction, Autom|/ A. Więckowski // ConStruct. 2020. Vol. 111. 103051. https://doi.org/10.1016/j. autcon.2019.103051. Więckowski, A. Automating CSA cement-based reinforced monolithic ceiling construction, Autom|/ A. Więckowski // ConStruct. 2020. Vol. 111. 103051. https://doi.org/10.1016/j. autcon.2019.103051. Pooni, J. Novel use of calcium sulfoaluminate (CSA) cement for treating problematic soils/ J. Pooni, D. Robert, F. Giustozzi, S. Setunge, Y.M. Xie, J. Xia// Construct. Build. Mater.2020. Vol.260. 120433, https://doi.org/10.1016/j. conbuildmat.2020.120433. Pooni, J. Novel use of calcium sulfoaluminate (CSA) cement for treating problematic soils/ J. Pooni, D. Robert, F. Giustozzi, S. Setunge, Y.M. Xie, J. Xia// Construct. Build. Mater.2020. Vol.260. 120433, https://doi.org/10.1016/j. conbuildmat.2020.120433. Mohan, M.K. Early age hydration, rheology and pumping char-acteristics of CSA cement-based 3D printable concrete, / M.K. Mo-han., A.V. Rahul., G. De Schutter., K. Van Tittelboom // Construct. Build. Mater. 2021. Vol.275. 122136, https://doi.org/10.1016/ j. conbuildmat.2020.122136. Mohan, M.K. Early age hydration, rheology and pumping char-acteristics of CSA cement-based 3D printable concrete, / M.K. Mo-han., A.V. Rahul., G. De Schutter., K. Van Tittelboom // Construct. Build. Mater. 2021. Vol.275. 122136, https://doi.org/10.1016/ j. conbuildmat.2020.122136. Sirtoli, D. Shrinkage and creep of high-performance concrete based on calcium sulfoaluminate cement/ D. Sirtoli., M. Wyrzykow-ski., P. Riva., S. Tortelli., M. Marchi., P. Lura// Cem. Concr. Comps. 2019. Vol. 78. p. 61–73. https://doi.org/10.1016/j. cemconcomp.2019.02.006. Sirtoli, D. Shrinkage and creep of high-performance concrete based on calcium sulfoaluminate cement/ D. Sirtoli., M. Wyrzykow-ski., P. Riva., S. Tortelli., M. Marchi., P. Lura// Cem. Concr. Comps. 2019. Vol. 78. p. 61–73. https://doi.org/10.1016/j. cemconcomp.2019.02.006. Valenti, G. High-temperature synthesis of calcium sulphoaluminate from phosphogypsum, G. Valenti, L. Santoro, R. Garofano//Thermochim. Acta 1987. Vol 113. P. 269–275. Valenti, G. High-temperature synthesis of calcium sulphoaluminate from phosphogypsum, G. Valenti, L. Santoro, R. Garofano//Thermochim. Acta 1987. Vol 113. P. 269–275. Ma, S. Alite-ye'elimite cement: synthesis and mineralogical analysis// S. Ma., R. Snellings., X. Li., X. Shen., K.L. Scrivener // Cem. Concr. Res. 2013. Vol. 45. P. 15–20. Ma, S. Alite-ye'elimite cement: synthesis and mineralogical analysis// S. Ma., R. Snellings., X. Li., X. Shen., K.L. Scrivener // Cem. Concr. Res. 2013. Vol. 45. P. 15–20. Xuerun, Li. Kinetics of calcium sulfoaluminate formation from tricalcium aluminate, calcium sulfate and calcium oxide// Li Xuerun., Yu Zhang., Shen Xiaodong., Wang Qianqian., Pan Zhigang., Cement and Concrete Research 2014. Vol.55. p. 79-87. https://doi.org/10.1016/j.cemconres.2013.10.006. Xuerun, Li. Kinetics of calcium sulfoaluminate formation from tricalcium aluminate, calcium sulfate and calcium oxide// Li Xuerun., Yu Zhang., Shen Xiaodong., Wang Qianqian., Pan Zhigang., Cement and Concrete Research 2014. Vol.55. p. 79-87. https://doi.org/10.1016/j.cemconres.2013.10.006. Мин Хеин Хтет. Получение сульфоалюминатного цемента и исследование его свойств/ Мин Хеин Хтет, Е.Н. Потапова // Международное аналитическое образование АЛИТинформ: Цемент. Бетон. Сухие строительные смеси. 2023. Т.3. № 72.С. 2-9. Min Hein Htet. Poluchenie sul'foalyuminatnogo cementa i issledovanie ego svoystv/ Min Hein Htet, E.N. Potapova // Mezhdunarodnoe analiticheskoe obrazovanie ALITinform: Cement. Beton. Suhie stroitel'nye smesi. 2023. T.3. № 72.S. 2-9. Shen, X. High-strength Portland Cement Clinker and Preparation Method/ X. Shen, X. Li, J. Xu,W. Xu, Y. Zhang, Y. Zhou//Nanjing University of Technology, Peop. Rep. China, 2013, p. 10. Shen, X. High-strength Portland Cement Clinker and Preparation Method/ X. Shen, X. Li, J. Xu,W. Xu, Y. Zhang, Y. Zhou//Nanjing University of Technology, Peop. Rep. China, 2013, p. 10. Мамыкин, П. С. Кинетика образования силикатов в системе CaO – SiO2/ П. С. Мамыкин, С. Г. Златкин // Журнал физической химии. 1937. Т.9. №3. С. 393 – 406. Mamykin, P. S. Kinetika obrazovaniya silikatov v sisteme CaO – SiO2/ P. S. Mamykin, S. G. Zlatkin // Zhurnal fizicheskoy himii. 1937. T.9. №3. S. 393 – 406. Потапова, Е. Н. Интенсификация процесса алитообразования в оксидно-солевых расплавах [Текст]: дис …канд. техн. наук: 05.17.11 /Е. Н. Потапова. М., 1983. 271 с. Potapova, E. N. Intensifikaciya processa alitoobrazovaniya v oksidno-solevyh rasplavah [Tekst]: dis …kand. tehn. nauk: 05.17.11 /E. N. Potapova. M., 1983. 271 s. Мин Хеин Хтет, Кинетика минералообразования при синтезе сульфоалюминатного клинкера/ Мин Хеин Хтет, Е. Н. Потапова, И.Ю Бурлов// Успехи в химии и химической техноло-гии.2022., Т. 36., № 3(252)., С. 106-108. Min Hein Htet, Kinetika mineraloobrazovaniya pri sinteze sul'foalyuminatnogo klinkera/ Min Hein Htet, E. N. Potapova, I.Yu Burlov// Uspehi v himii i himicheskoy tehnolo-gii.2022., T. 36., № 3(252)., S. 106-108.