THE INFLUENCE OF GYPSUM DIHYDRATE AND PLASTICIZING ADDITIVES ON THE PROPERTIES OF SULFOALUMINATE CEMENTS
Abstract and keywords
Abstract:
Within the framework of the conducted research, a comprehensive assessment of the influence of chemical plasticizing additives of differ-ent natures on the rheological and physico-mechanical properties of special cement systems based on calcium sulfoaluminate clinker was performed. The objects of the study were the polycarboxylate ether-based superplasticizer MELMENT F10 and the new generation hyper-plasticizer MELFLUX 4930F. The study involved varying two key parameters: the type and dosage of the plasticizing additive, and the amount of dihydrate gypsum (CaSO₄·2H₂O) introduced into the binder composition. Gypsum plays a critical role in regulating the hardening kinetics and the formation of the final structure of calcium sulfoaluminate cement. As a result of the experiments, a clear dependence between the nature of the additive and the construction-technical characteristics of the composites was established. The hyperplasticizer MELFLUX 4930F demonstrated significantly higher efficiency compared to the superplasticizer MELMENT F10. Its application provided a significant reduction in the water demand of the mixtures while simultaneously improving workability, which positively affected the density and strength of the hardened paste. Based on the totality of the obtained data (compressive and flexural strength, standard consistency of cement paste, setting times), the optimal formulation composition was determined. The best results were recorded for the composition containing 5% dihydrate gypsum by weight of the binder and 0.5% hyperplasticizer MELFLUX 4930F. This particular combination ensured the formation of a cement paste with maximum strength indicators at early and late hardening ages, as well as high density and durability.

Keywords:
sulfoaluminate clinker, natural gypsum stone, plasticizing additives, standard consistency, setting times
References

1. Kuznecova T.V. Alyuminatnye i sul'foalyuminatnye cementy. Moskva: Stroyizdat, 1986. 208 s.

2. Krivoborodov, Y. Synthesis of high alumina cement based on metallurgy wastes / Y. Krivoborodov, S. Samchenko // IOP Conference Series: Materials Science and Engineering: International Conference on Construction, Architecture and Technosphere Safety - 2. Building Materials and Products, Chelyabinsk, 25–27 sentyabrya 2019 goda. Vol. 687, 2. – Chelyabinsk: Institute of Physics Publishing, 2019. – P. 022034. – https://doi.org/10.1088/1757-899X/687/2/022034 . – EDN JEPJSS.

3. Samchenko, S. V. Usage aluminiferous waste in the production of aluminate cements / S. V. Samchenko, Y. R. Krivoborodov, I. Y. Burlov // 17th international multidisciplinary scientific geoconference SGEM 2017, Albena, Bulgaria, 29 iyunya – 05 2017 goda. Vol. 17. – Albena, Bulgaria: Obschestvo s ogranichennoy otvetstvennost'yu STEF92 Tehnolodzhi, 2017. – P. 465-472. – https://doi.org/10.5593/sgem2017/62/S26.059 . – EDN XZUNFU.

4. Kuznecova, T. V. Himiya, sostav i svoystva special'nyh cementov / T. V. Kuznecova, Yu. R. Krivoborodov, S. V. Samchenko // Himiya i himicheskaya tehnologiya na rubezhe tysyacheletiy : materialy nauchno-prakticheskoy konferencii, Tomsk, 03–04 oktyabrya 2000 goda / Tomskiy politehnicheskiy universitet (TPU). Tom 1. – Tomsk: Nacional'nyy issledovatel'skiy Tomskiy politehnicheskiy universitet, 2000. – S. 96-98. – EDN TOEXOZ.

5. Sulfoaluminate cements based on technogenic waste / S. Samchenko, Yu. Krivoborodov, I. Burlov, S. Krivoborodova // 18th International Multidisciplinary Scientific GeoConference SGEM 2018: Conference proceedings, Albena, Bulgaria, 02–08 iyulya 2018 goda. Vol. 18. – Albena, Bulgaria: Obschestvo s ogranichennoy otvetstvennost'yu STEF92 Tehnolodzhi, 2018. – P. 341-348. – https://doi.org/10.5593/sgem2018/6.3/S26.045 . – EDN BISKUJ.

6. Krivoborodov Yu.R., Burlov I.Yu. Svoystva rasshiryayuschegosya cementa v zavisimosti ot parametrov proizvodstv // Suhie stroitel'nye smesi, 2015. №2. S. 39-41.

7. Krivoborodov, Yu.R. Fiziko-himicheskie svoystva sul'fatirovannyh klinkerov: Analiticheskiy obzor / Yu. R. Krivoborodov, S. V. Samchenko. – Moskva: VNIIESM, 1991. – 55 s. – (Cementnaya promyshlennost'; Vypusk 2). – EDN TSRXOD.

8. Zaharov S.A. Optimizaciya sostavov betonov vysokoeffektivnymi polikarboksilatnymi plastifikatorami // Stroitel'nye materialy, 2008, № 3, C. 42-43.

9. Ruzhickaya A.V., Potapova E.N., Vliyanie dobavok-plastifikatorov na svoystva belogo portlandcementa // Mezhdunarodnyy nauchnyy zhurnal «Innovacionnaya nauka», 2009, S. 14-23

10. Samchenko, S. V. Formirovanie i genezis struktury cementnogo kamnya / S. V. Samchenko. – 2-e izdanie. – Moskva: Nacional'nyy issledovatel'skiy Moskovskiy gosudarstvennyy stroitel'nyy universitet, 2020. – 288 s. – ISBN 978-5-7264-2808-6. – EDN KCBIBU.

11. Samchenko, S. V. Rol' ettringita v formirovanii i genezise struktury kamnya special'nyh cementov / S. V. Samchenko ; Feder. agentstvo po obrazovaniyu, RHTU im. D. I. Mendeleeva, Izdat. centr. – Moskva: Ros. him.-tehnol. un-t im. D. I. Mendeleeva, 2005. – 154 s. – ISBN 5-7237-0514-0. – EDN QNDVZV.

12. Samchenko, S. V. Vliyanie superplastifikatora na morfologiyu kristallov ettringita / S. V. Samchenko, E. M. Makarov // Tehnika i tehnologiya silikatov. – 2015. – T. 22, № 2. – S. 17-21. – EDN UACCCX.

13. Samchenko, S. V. Obrazovanie i rost kristallov ettringita v prisutstvii polimernyh funkcional'nyh dobavok / S. V. Samchenko, E. M. Makarov // Uspehi sovremennoy nauki i obrazovaniya. – 2016. – T. 5, № 12. – S. 118-122. – EDN XHEBOF.

14. Samchenko, S.V. Vliyanie plastifikatora na processy perekristallizacii pri tverdenii alyuminata kal'ciya / S.V. Samchenko, S.Yu. Krivoborodova // Tehnika i tehnologiya silikatov. – 2017. – T. 24, № 3. – S. 25-30. – EDN ZERBLL.

15. Samchenko, S. V. Influence of fineness of expansive components on cement properties / S. V. Samchenko, D. A. Zorin // Cement, Wapno, Beton. – 2008. – No. 5. – P. 254-257. – EDN RYAPJJ.

16. Analiz strukturno-fazovogo sostoyaniya monoalyuminata kal'ciya / Yu. A. Abzaev, Yu. S. Sarkisov, T. V. Kuznecova [i dr.] // Inzhenerno-stroitel'nyy zhurnal. – 2014. – № 3(47). – S. 56-62. – https://doi.org/10.5862/MCE.47.6 . – EDN SBZAHX.

17. Samchenko, S. V. Features of the formation of crystalline hydrosulfoaluminates during hydration of stoichiometric mixtures of calcium aluminates with calcium sulfate / S. V. Samchenko, A. V. Korshunov // Construction and Building Materials. – 2023. – Vol. 393. – P. 132102. – https://doi.org/10.1016/j.conbuildmat.2023.132102 . – EDN CRATKC.

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