A complex of physical and chemical methods of analysis has been employed to investigate the effect of fine-grain silica, obtained from copper-nickel smelter slag, on hardening and phase composition of magnesia oxychloride binder. In the composition of the magnesia cement, modified by the addition of silica, along with the main products of hardening binder found oxyhydrochloride compound of magnesium and silicon, which contributes to the improvement of water resistance of cement stone. The average composition of the magnesia binder, modified by the addition of silica, is reported.
magnesia binders, amorphous silica, strength, water resistance, hydration, phase composition
1. Smirnov B. I., Solov'eva E. S., Segalova E. E. Issledovanie himicheskogo vzaimodeystviya okisi magniya s rastvorami hloristogo magniya razlichnyh koncentraciy // ZhPH. - 1967. - T. 40, vyp. 3. - S. 505-515.
2. Vyrodov I. P., Bergman A. G. K voprosu o tverdenii magnezial'nyh vyazhuschih // ZhPH. - 1959. - T. 32, vyp. 4. - S. 716-723.
3. Vyrodov I. P. Differencial'no-termicheskoe issledovanie troynoy sistemy MgO-MgCl2-H2O // ZhPH. - 1961. - T. 34, vyp. 6. - S. 1208-1218.
4. Vyrodov I. P. O strukturoobrazovanii magnezial'nyh cementov // ZhPH. - 1960. - T. 33, vyp. 11. - S. 2399-2404.
5. Osobobystrotverdeyuschee magnezial'noe vyazhuschee / V. I. Korneev, A. P. Sizonenko, I. N. Medvedeva [i dr.] // Cement. - 1997. - № 2. - S. 25-28.
6. Fedorov N. F., Andreev M. A. Obzhigovyy magnezial'no-hloridnyy cement // Cement i ego primenenie. - 2006. - № 3. - S. 76-78.
7. Zuev V. V., Pocelueva L. N., Goncharov Yu. D. Kristalloenergetika kak osnova ocenki svoystv tverdotel'nyh materialov. - SPb.: Prospekt nauki, 2006. - 139 s.
8. Kramar L. Ya., Chernyh T. N., Trofimov B. Ya. Osobennosti tverdeniya magnezial'nogo vyazhuschego // Cement i ego primenenie. - 2006. - № 5. - S. 58-61.
9. Potapov V. V., Shitikov E. S., Trutnev E. S. Ispol'zovanie zoley i poroshkov kremnezema, poluchennyh iz gidrotermal'nyh rastvorov, kak nanodobavok v cementy // Himicheskaya tehnologiya. - 2010. - № 10. - S. 597-604.
10. Rol' amorfnogo mikrokremnezema v processah strukturoobrazovaniya i uprochneniya betonov / V. V. Babkov, R. R. Sahibgareev, Rom. R. Sahibgareev [i dr.] // Stroitel'nye materialy. - 2010. - № 6. - S. 44-46.
11. Reaction products of MgO and microsilica cementitious materials at different temperatures / Wei Jiangxiong, Yu Qijun, Zhang Wensheng [et al.] // Journal of Wuhan University of Technology Mater. Sci. Ed. - 2011. - Vol. 26, is. 4. - P. 745-748.
12. Brykov A. S. Silikatnye i kremnezemsoderzhaschie rastvory i ih primenenie // Tehnika i tehnologiya silikatov. - 2010. - T. 17, № 1. - S. 2-18.
13. Pat. 2246464 Rossiyskaya Federaciya, MPK7 S04V28/30. Kompoziciya na osnove magnezial'nogo vyazhuschego / Leont'ev I. V., Kramar L. Ya., Korolev A. S. [i dr.]. - № 2001122345/03; zayavl. 08.08.01; opubl. 20.02.05, Byul. № 5.
14. Vodostoykie magnezial'nye vyazhuschie na osnove produktov pererabotki shlaka cvetnoy metallurgii / A. G. Kasikov, V. V. Tyukavkina, B. I. Gurevich [i dr.] // Stroitel'nye materialy. - 2013. - № 11. - S. 70-73.
15. Pat. 2428390 Rossiyskaya Federaciya, MPK S04V 9/06 (2006.01). Magnezial'noe vyazhuschee / Tyukavkina V. V., Kasikov A. G., Gurevich B. I. [i dr.]. - № 2010127680/03; zayavl. 05.07.10; opubl. 10.09.11, Byul. № 25.
16. Poluchenie amorfnogo kremnezema iz shlakov cvetnoy metallurgii i ego ispol'zovanie dlya magnezial'nyh vyazhuschih / V. V. Tyukavkina, A. G. Kasikov, B. I. Gurevich [i dr.] // Himicheskaya tehnologiya. - 2014. - № 3. - S. 167-172.
17. Tyukavkina V. V., Gurevich B. I. Vliyanie rezhimov obzhiga dolomita na svoystva magnezial'nogo vyazhuschego // Suhie stroitel'nye smesi. - 2014. - № 1. - S. 33-36.
18. Smirnov B. I., Solov’eva E. S., Segalova E. E. The study of the chemical interaction of magnesium oxide with magnesium chloride solutions of different concentrations. ZhPKh, 1967, vol. 40, is. 3, pp. 505-515 (in Russian).
19. Vyrodov I. P., Bergman A. G. To the question of hardening of magnesia binders. ZhPKh, 1959, vol. 32, is. 4, pp. 716-723 (in Russian).
20. Vyrodov I. P. Differential thermal study of the ternary system MgO-MgCl2-H2O. ZhPKh, 1961, vol. 34, is. 6, pp. 1208-1218 (in Russian).
21. Vyrodov I. P. About the structure formation of magnesia cements. ZhPKh, 1960, vol. 33, is. 11, pp. 2399-2404 (in Russian).
22. Korneev V. I., Sizonenko A. P., Medvedeva I. N., et al. Especially rapid-setting magnesia binder. Tsement, 1997, no. 2, pp. 25-28 (in Russian).
23. Fedorov N. F., Andreev M. A. Fired magnesia-chloride cement. Tsement i ego primenenie, 2006, no. 3, pp. 76-78 (in Russian).
24. Zuev V. V., Potselueva L. N., Goncharov Yu. D. Kristalloenergetika kak osnova otsenki svoystv tverdotel’nykh materialov [Crystal energetics as a basis for assessment the properties of solid-state materials]. SPb.: Prospekt nauki, 2006, 139 p (in Russian).
25. Kramar L. Ya., Chernykh T. N., Trofimov B. Ya. Features hardening magnesia binder. Tsement i ego primenenie, 2006, no. 5, pp. 58-61 (in Russian).
26. Potapov V. V., Shitikov E. S., Trutnev E. S. Use of sols and silica powders, obtained from hydrothermal solutions, as nano-additives to cement. Khimicheskaya tekhnologiya, 2010, no. 10, pp. 597-604 (in Russian).
27. Babkov V. V., Sakhibgareev R. R., Sakhibgareev Rom. R., et al. The role of amorphous microsilica in the processes of structure formation and hardening of concrete. Stroitel’nye materialy, 2010, no. 6, pp. 44-46 (in Russian).
28. Wei Jiangxiong, Yu Qijun, Zhang Wensheng, et al. Reaction products of MgO and microsilica cementitious materials at different temperatures. Journal of Wuhan University of Technology Mater. Sci. Ed, 2011, vol. 26, is. 4, pp. 745-748.
29. Brykov A. S. Silicate and silica-containing solutions and their application. Tekhnika i tekhnologiya silikatov, 2010, vol. 17, no. 1, pp. 2-18 (in Russian).
30. Patent RF 2246464. Kompozitsiya na osnove magnezial’nogo vyazhushchego [Composition based on magnesia binder]. Leont’ev I. V., Kramar L. Ya., Korolev A. S., et al. Declared 08.08.01. Published 20.02.05. Bulletin no. 5 (in Russian).
31. Kasikov A. G., Tyukavkina V. V., Gurevich B. I., et al. Water-resistant magnesia binders based products slag processing non-ferrous metallurgy. Stroitel’nye materialy, 2013, no. 11, pp. 70-73 (in Russian).
32. Patent RF 2428390. Magnezial’noe vyazhushchee [Magnesia binder]. Tyukavkina V. V., Kasikov A. G., Gurevich B. I., et al. Declared 05.07.10. Published 10.09.11. Bulletin no. 25 (in Russian).
33. Tyukavkina V. V., Kasikov A. G., Gurevich B. I., et al. Manufacture of amorphous silica from non-ferrous metallurgy slag and it use for magnesia binders. Khimicheskaya tekhnologiya, 2014, no. 3, pp. 167-172 (in Russian).
34. Tyukavkina V. V., Gurevich B. I. Effect of calcination regimes of dolomite on magnesia binder properties. Sukhie stroitel’nye smesi, 2014, no. 1, pp. 33-36 (in Russian).