The aim of the study was to establish the influence of the plasticizer based on polycarboxylate on the formation and morphology of the formed hydrated phases. The mechanism of structure formation at the hydration of 12CaO∙7Al2O3 in the presence of the plasticizer, which consists of the formation of fine poorly crystallized hexagonal crystals of calcium aluminate hydrate. The presence of the superplasticizer in the composition gidratirovana calcium aluminate slows down the nucleation and growth of crystalline hydrates-formed on the surface of the partition liquid and solid phases of the film, creating structural and mechanical barrier, which leads to slow saturation of the liquid phase, but contributes to the formation of a larger number of crystallization centers and the concurrent growth of small crystals as hexagonal and cubic habit.
calcium aluminate, crystal hydrate morphology and formation, hexagonal and cubic of calcium aluminate hydrate, recrystallization, plasticizer
1. Kuznecova T. V. Alyuminatnye i sul'foalyuminatnye cementy. - M.: Stroyizdat, 1986. - 208 s.
2. Ukrainczyk N., Matusinović T. Thermal properties of hydrating calcium aluminate cement pastes. Original Research Article // Cement and Concrete Research. - 2010. - Vol. 40, no. 1. - P. 128-136.
3. The influence of filler type and surface area on the hydration rates of calcium aluminate cement / G. Puerta-Falla, A. Kumar, L Gomez-Zamorano [et al.] // Construction and Building Materials. -2015. - Vol. 96, October - P. 657-665.
4. Klaus S. R., Neubauer J., Goetz-Neunhoeffer F. Hydration kinetics of CA2 and CA - Investigations performed on a synthetic calcium aluminate cement. // Cement and Concrete Research, 2013. - Vol. 43, January. - P. 62-69
5. Samchenko S. V., Zorin D. A., Borisenkova I. V. Vliyanie dispersnosti glinozemistogo shlaka i sul'foalyuminatnogo klinkera na formirovanie struktury cementnogo kamnya // Tehnika i tehnologiya silikatov. - 2011. - T. 18, № 2. - C. 12-14.
6. Kuznecova T. V., Krivoborodov Yu. R., Samchenko S. V. Himiya, sostav i svoystva special'nyh cementov // Materialy nauchno-prakticheskoy konferencii «Himiya, himicheskaya tehnologiya na rubezhe tysyacheletiya». - Tomsk. - 2000. - № 1. - S. 96-98.
7. Sovershenstvovanie svoystv glinozemistogo cementa i ego primenenie / S. V. Samchenko, T. A. Lyutikova, T. V. Kuznecova [i dr.] // Cement i ego primenenie. - 2006. - № 3. - S. 46-48.
8. Gusev B. V., Krivoborodov Yu. R., Samchenko S. V. Tehnologiya portlandcementa i ego raznovidnostey: ucheb. posobie. - M.: NIU MGSU, 2016. - 112 s.
9. Taylor X. Cement Chemistry. - London, 1990. - 607 p.
10. Falzone G, Balonis M., Sant G. X-AFm stabilization as a mechanism of bypassing conversion phenomena in calcium aluminate cements Original Research Article // Cement and Concrete Research. - 2015. - Vol. 72, June. - P. 54-68.
11. The Influence of Sodium Hexametaphosphate (Na6P6O18) on Hydration of Calcium Aluminate Cement Under Hydrothermal Condition / M. Palou, E. Kuzielová, M. Žemlička [et al.]. Original Research Article // Procedia Engineering. - 2016. - Vol. 151. - P. 119-126.
12. Önder Kırca, İ. Özgür Yaman, Mustafa Tokyay. Compressive strength development of calcium aluminate cement-GGBFS blends. Original Research Article // Cement and Concrete Composites. - 2013. - Vol. 35, is. 1, January. - P. 163-170.
13. Nasser Y., Mostafa, Z. I. Zaki, Omar H. Abd Elkader. Chemical activation of calcium aluminate cement composites cured at elevated temperature. Original Research Article // Cement and Concrete Composites. - 2012. - Vol. 34, is. 10, November. - P. 1187-1193.
14. Małgorzata Niziurska, Jan Małolepszy, Grzegorz Malata. The Influence of Lithium Carbonate on Phase Composition of Calcium Aluminate Cement Paste. Original Research Article // Procedia Engineering. - 2015. - Vol. 108. - P. 363-370.
15. Kuznecova T. V., Samchenko S. V. Mikroskopiya materialov cementnogo proizvodstva. - M.: MIKHiS, 2007. - 304 s.