UDK 691.175 Пластмассы. Полимерные материалы
GRNTI 67.09 Строительные материалы и изделия
OKSO 08.06.01 Техника и технологии строительства
BBK 383 Строительные материалы и изделия
TBK 5415 Строительные материалы и изделия. Производство стройматериалов
The influence of supramolecular structures on the optical characteristics of polymers is considered. Studies of fluorine-containing acrylic polymers with fluorine-containing electro-optical chromophores in the side chain have shown that they should have a fibrillar supramolecular structure. The preservation of the fibrillar structure determines the technical condi-tions (temperature range) for the operation of high-speed integrated optical modulators and switches. The polymers con-sidered in the work were divided into three types according to the degree of polarization kp: polymers for which kp1 = 1.39; polymers with kp2 = <1.17>; polymers with kp3 = 1.003. To calculate nonlinear optical characteristics, the Jepsen equation was used. The possibility of calculating the polarizability of a polymer x from experimental values of the dielec-tric constant εexp is shown. The approach being developed can be used in medicine and biology to analyze the functioning of neurons (tubulin protein) and identify the causes of age-related changes in human memory. The latter is due to plastici-zation of tubulin and disruption of its fibrillar structure over time at brain temperature.
dielectric constant, polarizability, supramolecular structures, neuron, tubulin, chromophores.
1. Gulyaev Yu.V., Bugaev A.S., Bystrov R.P., Nikitov S.A., Cherepenin V.A. Mikro- i nanoelektronika v si-stemah radiolokacii, Monografiya. Moskva: Izda-tel'stvo «Radiotehnika» – 2014 – 479 s. ISBN 978-5-88070-377-7.
2. Zaycev D.F. Nanofotonika i ee primenenie. Moskva: Firma «AKTEON» – 2012 – 445 s. ISBN 978-5-9905835-2-8.
3. Zaycev D.F. Fotonokristallicheskie ustroystva analogovoy nanofotoniki // Antenny. – 2008, – Vyp. 6. – S. 81-88.
4. Bystrov R. P., Sokolov S. A., Cherepenin V. A. Si-stemy i ustroystva na osnove radiofotoniki prime-nitel'no k radiolokacii // Zhurnal radioelektroni-ki [elektronnyy zhurnal] – 2017, – №6.
5. Zheng C.T., Zhang L.J., Qv L.C., Liang L., Ma C.S., Zhang D.M., Cui Z.C, Nanosecond polymer Mach-Zehnder interferometer electro-optic modulator using op-timized micro-strip line electrode // Opt. Quant. Electron – 2013, – 45(3). – P. 279. DOIhttps://doi.org/10.1007/s11082-012-9629-1.
6. Nazmieva G.N., Vakhonina T.A., Ivanova N.V., Mukhtarov A.Sh., Smirnov N.N., Yakimansky A.V., Ba-lakina M.Yu., Sinyashin O.G. Testing of the ways for syn-thesis of new nonlinear optical epoxy-based polymers with azochromo-phores in the side chain // European Pol-ymer Journal – 2015, – Vol. 63 – P. 207-216.
7. Sokolov V.I., Ahmanov A.S., Asharchuk I.M., Goryachuk I.O., Haydukov K.V., Nazarov M.M. Formirovanie kanal'nyh opticheskih volnovodov v polimetilme-takrilate s vnedrennym elektroopticheskim hromo-forom DR13 metodom foto osvetleniya // Optika i spektroskopiya – 2017, – 122, №3 – C. 128–134.
8. Michel S., Zyss J., Ledoux-Rak I., Nguyen C.T. High-performance electro-optic modulators realized with a commercial side-chain DR1-PMMA electro-optic copol-ymer // Proceedings of SPIE, Organic Photonic Materials and Devices XII – 2010, – Vol. 7599. DOIhttps://doi.org/10.1117/12.841339.
9. Sokolov V.I., Ahmanov A.S., Vasilenko E.S., Gorya-chuk I.O. Molchanova S.I., Pogodina Yu.E., Polunin E.V., Sintez i issledovanie opticheskih svoystv ftor-soderzhaschego hromofora dispersnyy oranzhevyy DO1 // Fluorine Notes – 2018, – Vol. 5, №120. – S. 1-2.
10. Sokolov V.I., Ahmanov A.S., Asharchuk I.M., Gorya-chuk I.O., Zavarzin I.V., Pogodina Yu.E., Polunin E.V. Lazernoe formirovanie svetovodov v elektrooptiche-skih polimerah s ftorsoderzhaschimi hromoforami v bokovoy cepi // Fluorine Notes – 2018, – Vol. 6, №121. – S. 5-6.
11. Batuev A.S. Fiziologiya vysshey nervnoy deyatel'-nosti i sensornyh sistem. 3-e izd. SPb: Piter. – 2010, – S. 317.
12. Zefirov T.L., Ziyatdinova N.I., Kupcova A.M. Fi-ziologicheskie osnovy pamyati. Razvitie pamyati u de-tey i podrostkov. Uchebno-metodicheskoe posobie. Ka-zan' 2015
13. Askadskiy A.A., Matveev Yu.I., Maceevich T.A. Vliyanie struktury polimernyh nanokompozitov na ih pokazatel' prelomleniya i dielektricheskuyu pro-nicaemost' // Vysokomolekulyarnye soedineniya – 2018, – T. 60A, №6. – S. 461-469. DOIhttps://doi.org/10.1134/S2308112019010012.
14. Jepsen D.W. Calculation of the Dielectric Constant of a Fluid by Cluster Expansion Methods // J. Chem. Phys. – 1966. Vol. 44, № 2. – Pp. 774-781. DOIhttps://doi.org/10.1063/1.1726758.
15. Matveev Yu.I., Askadskiy A.A. Raschetnyy sposob ocenki razmerov elementov nadmolekulyarnoy struk-tury polimerov // Vysokomolekulyarnye soedineniya – 1989, T. 31A, №3 – S. 526-532.
16. Slonimskiy G.L., Korshak V.V., Vinogradova S.V., Kitaygorodskiy A.I., Askadskiy A.A., Salazkin S.N., Belavceva E.M. Fiziko-himicheskie puti regulirova-niya nadmolekulyarnyh struktur i mehanicheskih svoystv amorfnyh poliarilatov na osnove fenol-ftaleina i ego proizvodnyh // Vysokomolekulyarnye soedineniya – 1967, T. 9A, №2. – S. 402-408.
17. Finkel'shteyn A. V., Pticyn O. B. Fizika belka. – Moskva: KDU – 2005, – S. 138–146. ISBN 5-98227-065-2.
18. Askadskiy A.A., Kondraschenko V.I. Komp'yuternoe materialovedenie polimerov. Tom 1, Atomnyy i mo-lekulyarnyy urovni. Moskva: Nauchnyy mir – 1999. – 543 s.
19. Sokolov V.I., Ahmanov A.S., Asharchuk I.M., Gorya-chuk I.O., Molchanova S.I., Pogodina Yu.E., Polunin E.V., Haydukov K.V. Ftorsoderzhaschie akrilovye po-limery s ftorsoderzhaschimi elektroopticheskimi hromoforami v bokovoy cepi // Fluorine Notes – 2020, №129. – 1-2.
20. Matveev Yu.I., Aver'yanova E.V. Ocenka skorosti rosta aterosklero-ticheskih blyashek v stenkah krove-nosnyh sosudov. // Tehnologii zhivyh sistem – 2023, – T. 20, №4 – S. 43-48
21. Davydov V.V., Komarov O.S. Biohimiya nervnoy tkani, Moskva: Izdatel'stvo «Belyy Veter» – 2018, – 56 c. ISBN 978-5-88458-370-2.
22. Matveev Yu.I., Askadskiy A.A. Poluchenie nanopo-ristyh struktur v teplostoykih polimernyh dielek-trikah dlya mikroelektroniki // Vysokomolekulyarnye soedineniya – 2003, T. 45A, №10. – S. 1707-1717.
